Hi Mark
I must admit that the sudden rise in pH sounds disturbing to me and rather contradictory to norms. Or at least to my own experience.
An increase in pH level may occur when ripening with mould - but then we speak about an effect over weeks - not four days.
And considering the average dosage of fermentable sugar in the Pepperoni, there should be plenty of acid formation to ensure a
permanent drop below pH 5.3 by now.
What I continuously wonder about is the high start pH of 7,2.
I´m pretty sure that a german producer of raw hams and salami would reject meat with such a high pH.
Optimally it should have been between 6,2 and 5,8.
7.2 is good if you want to make emulsified sausages Frankfurter / Hotdog style with a good water binding - but not for salami.
Also I wonder if it might be overtaxing the Biobak Ultra Plus to let it work from such a high outset pH as 7.2 ( I better ask HQ about this topic
).
Perhaps a starter culture with a slightly more aggresive acidifyer strain (like Curvatus or Plantarum) would have been more appropriate in this situation, but I think the best thing for you would be to make sure thet the pH of the meat is not higher than 6.2 when you start preparing it.
Otherwise just follow your intentions of lowering temperature and humidity.
However, with the present high pH don´t expect the sausages to dry out right away, and I would not let the humidity get under 70- 75% for the next couple of days.